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The finding established that the GSH redox cycle is the primary intracellular antioxidant defence system in endothelial cells against peroxide-mediated oxidative stress, and remains a foundational reference for endothelial oxidative stress research using GSH manipulation

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In the glycolysis pathway, 3-PG is first oxidized to 3-phosphate hydroxy-pyruvate by phosphoglycerate dehydrogenase (PHGDH), then catalyzed to 3-phosphoserine by phosphoserine aminotransferase (PSAT1), and, finally, dephosphorylated to serine by 1-3-phosphoserine phosphatase (PSPH) [45]

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10.1021/tx500211x Chem

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