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Post-translational regulation of -ECS Feedback inhibition of enzyme activity by GSH has long been established in animals (Richman and Meister, 1975) and also occurs in plants (Hell and Bergmann, 1990

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Free Cu2+ is toxic (Fenton reactions, hydroxyl radicals), but the GHK-Cu complex is stable, diffusible and delivers copper in a targeted manner to copper-dependent metalloenzymes: lysyl oxidase (collagen/elastin crosslinking), Cu/Zn superoxide dismutase (SOD1, antioxidant defence), tyrosinase (controlled melanogenesis), dopamine-beta-hydroxylase