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The intrinsic pathway is typically activated by TNF- or oxidative stress, which disrupts the Bcl-2-associated X protein to B-cell lymphoma 2 (Bax/Bcl-2) ratio, promoting mitochondrial outer membrane permeabilization (MOMP) and cytochrome c release (Tait and Green, 2010), which subsequently activates caspase-9 and initiates the apoptotic cascade (Martinou and Youle, 2011)

10.1007/BF02426954 Vergauwen B, Pauwels F, Vaneechoutte M, Van Beeumen JJ: Exogenous glutathione completes the defense against oxidative stress in Haemophilus influenzae

Ferroptosis can occur due to the impairment of GSH-dependent lipid peroxidation repair system, in addition to PUFA-mediated signaling

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S-acetyl and sustained-release forms fall somewhere between, though head-to-head timing data is limited