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While smoking certainly has an adverse effect directly on your teeth, the most detrimental impact occurs to the oral structures (gums and jawbone) that hold your teeth in place

We also know that tobacco smoke triggers aberrant immune responses, by increasing the levels of eosinophils (a type of white blood cell involved in allergy phenomena) and the production of pro-inflammatory agents (TNF-, IL-6, etc.), which would directly impact the skin's protective barrier